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Chelyabinskiy Fiziko-Matematicheskiy Zhurnal, 2018, Volume 3, Issue 2, Pages 212–218
DOI: https://doi.org/10.24411/2500-0101-2018-13207
(Mi chfmj100)
 

Physics

Ceramic materialsbased on compounds BaCe${}_{1-x}$M${}_x$O${}_{3-\delta}$ (M — Y${}^{3+}$, Pr${}^{3+}$, Nd${}^{3+}$, Sm${}^{3+}$, Gd${}^{3+}$)

E. A. Bulaeva, Yu. A. Lupitskaya, D. A. Kalganov

Chelyabinsk State University, Chelyabinsk, Russia
References:
Abstract: For barium cerate solid solutions BaCe${}_{1-x}$M${}_x$O${}_{3-\delta}$, realised by partial heterovalent substitution of Ce${}^{4+}$ ions by ions of yttrium and rare-earth metals (M — Pr${}^{3+}$, Nd${}^{3+}$, Sm${}^{3+}$, Gd${}^{3+}$) upon threating in air, the conditions for obtaining are studied. By the method of qualitative X-ray diffraction analysis, it was established that at a final synthesis temperature of 1373 K barium cerate compounds crystallize within the distorted perovskite-type structure. On the basis of X-ray diffraction analysis, parameters characterizing the structure of synthesized perovskite-like phases were determined. The ceramic properties (relative density, porosity, grain size) of the samples sintered at 1773 K were studied.
Keywords: solid solution, barium cerate, heterovalent substitution, X-ray diffraction analysis, perovskite-like phase, ceramics.
Funding agency Grant number
Russian Foundation for Basic Research 18-33-00269-мол_а
Received: 17.02.2018
Revised: 18.03.2018
Document Type: Article
UDC: 544.6.018.462.42
Language: Russian
Citation: E. A. Bulaeva, Yu. A. Lupitskaya, D. A. Kalganov, “Ceramic materialsbased on compounds BaCe${}_{1-x}$M${}_x$O${}_{3-\delta}$ (M — Y${}^{3+}$, Pr${}^{3+}$, Nd${}^{3+}$, Sm${}^{3+}$, Gd${}^{3+}$)”, Chelyab. Fiz.-Mat. Zh., 3:2 (2018), 212–218
Citation in format AMSBIB
\Bibitem{BulLupKal18}
\by E.~A.~Bulaeva, Yu.~A.~Lupitskaya, D.~A.~Kalganov
\paper Ceramic materials\\ based on compounds BaCe${}_{1-x}$M${}_x$O${}_{3-\delta}$ (M~--- Y${}^{3+}$, Pr${}^{3+}$, Nd${}^{3+}$, Sm${}^{3+}$, Gd${}^{3+}$)
\jour Chelyab. Fiz.-Mat. Zh.
\yr 2018
\vol 3
\issue 2
\pages 212--218
\mathnet{http://mi.mathnet.ru/chfmj100}
\crossref{https://doi.org/10.24411/2500-0101-2018-13207}
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