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Physics
Ceramic materialsbased on compounds BaCe${}_{1-x}$M${}_x$O${}_{3-\delta}$ (M — Y${}^{3+}$, Pr${}^{3+}$, Nd${}^{3+}$, Sm${}^{3+}$, Gd${}^{3+}$)
E. A. Bulaeva, Yu. A. Lupitskaya, D. A. Kalganov Chelyabinsk State University, Chelyabinsk, Russia
Abstract:
For barium cerate solid solutions BaCe${}_{1-x}$M${}_x$O${}_{3-\delta}$, realised by partial heterovalent substitution of Ce${}^{4+}$ ions by ions of yttrium and rare-earth metals (M — Pr${}^{3+}$, Nd${}^{3+}$, Sm${}^{3+}$, Gd${}^{3+}$) upon threating in air, the conditions for obtaining are studied. By the method of qualitative X-ray diffraction analysis, it was established that at a final synthesis temperature of 1373 K barium cerate compounds crystallize within the distorted perovskite-type structure. On the basis of X-ray diffraction analysis, parameters characterizing the structure of synthesized perovskite-like phases were determined. The ceramic properties (relative density, porosity, grain size) of the samples sintered at 1773 K were studied.
Keywords:
solid solution, barium cerate, heterovalent substitution, X-ray diffraction analysis, perovskite-like phase, ceramics.
Received: 17.02.2018 Revised: 18.03.2018
Citation:
E. A. Bulaeva, Yu. A. Lupitskaya, D. A. Kalganov, “Ceramic materialsbased on compounds BaCe${}_{1-x}$M${}_x$O${}_{3-\delta}$ (M — Y${}^{3+}$, Pr${}^{3+}$, Nd${}^{3+}$, Sm${}^{3+}$, Gd${}^{3+}$)”, Chelyab. Fiz.-Mat. Zh., 3:2 (2018), 212–218
Linking options:
https://www.mathnet.ru/eng/chfmj100 https://www.mathnet.ru/eng/chfmj/v3/i2/p212
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Abstract page: | 128 | Full-text PDF : | 41 | References: | 25 |
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